Jul
21
Harvard John A. Paulson School of Engineering and Applied Sciences researchers have developed a new method to dramatically extend the lifetime of organic aqueous flow batteries. The development improves the commercial viability of a technology that has the potential to safely and inexpensively store energy from renewable sources such as wind and solar.
Michael Aziz, the Gene and Tracy Sykes Professor of Materials and Energy Technologies at SEAS explained, “Organic aqueous redox flow batteries promise to significantly lower the costs of electricity storage from intermittent energy sources, but the instability of the organic molecules has hindered their commercialization. Now, we have a truly practical solution to extend the lifetime of these molecules, which is an enormous step to making these batteries competitive.”
The team’s research paper has been published in Nature Chemistry.
During the past decade, Aziz and Roy Gordon, the Thomas Dudley Cabot Professor of Chemistry and Professor of Materials Science, have collaborated to develop organic aqueous flow batteries using molecules known as anthraquinones, which are composed of naturally abundant elements such as carbon, hydrogen, and oxygen, to store and release energy.
Over the course of their research, the team discovered that these anthraquinones decompose slowly over time, regardless of how many times the battery has been used.
In previous work, the researchers found that they could extend the lifetime of one of these molecules, named DHAQ but dubbed the “zombie quinone” in the lab, by exposing the molecule to air. The team found that if the molecule is exposed to air at just the right part of its charge-discharge cycle, it grabs oxygen from the air and turns back into the original anthraquinone molecule – as if returning from the dead, hence the nickname.
But regularly exposing a battery’s electrolyte to air isn’t exactly practical, as it drives the two sides of the battery out of balance – both sides of the battery can no longer be fully charged at the same time.
To find a more practical approach, the researchers collaborated with chemists at the University of Cambridge in the U.K. to better understand how the molecules decompose and invented an electrical method of reversing the process.
The team found that if they performed a so-called deep discharge, in which the positive and negative terminals of the battery get drained so that the voltage difference between the two becomes zero, and then flipped the polarity of the battery, forcing the positive side negative and the negative side positive, it created a voltage pulse that could reset the decomposing molecules back to their original form.
The cycle of decomposition and recomposition. During normal charge and discharge, the zombie molecule oscillates between its DHAQ2- form (left) and its DHAQ4- form (bottom center). When it decomposes, it turns into DHA2- (right). A voltage pulse resets the decomposed molecules (right) back to their original form (left). Image Credit: Yan Jing/Harvard SEAS. Click image for the largest view or visit the University’s link above.
Yan Jing, a postdoctoral fellow at Harvard and co-first author of the paper noted, “Usually, in running other kinds of batteries, you want to avoid draining the battery completely because it tends to degrade its components. But we’ve found that this extreme discharge, up to actually reversing the polarity, can recompose these molecules – which was a surprise.”
The process works a bit like a pacemaker, periodically providing a shock to the system that revives decomposed molecules.
In the paper, the researchers demonstrated a net lifetime 17-times longer than previous research. In subsequent research, which refined the process, the researchers demonstrated an even greater increase in lifetime, up to 260-times longer, leading to a loss rate under 10% per year. That research has yet to be published.
“Getting to a single digit percentage of loss per year is really enabling for widespread commercialization because it’s not a major financial burden to top off your tanks by a few percent each year,” said Aziz.
Harvard’s Office of Technology Development has protected the intellectual property associated with this project and has licensed the technology and other related patents on quinone flow batteries to Quino Energy, a startup pursuing its commercial development.
The research team also demonstrated that this approach works for a range of organic molecules and for a range of deep discharge processes, both with and without polarity reversal. Next, the team aims to explore how much further they can extend the lifetime of DHAQ and other inexpensive anthraquinones that have been used in these systems.
Imre Gyuk, Director of the Department of Energy’s Office of Electricity Storage program said, “Flow batteries can be expected to be the next wave in storage technology beyond Lithium – particularly batteries with organic electrolytes. This work allows control of the decomposition process, thus greatly extending the lifetime and enabling applications for medium- and long-duration energy storage.”
The research was co-authored by Evan Wenbo Zhao, Marc-Antoni Goulet, Meisam Bahari, Eric M. Fell, Shijian Jin, Ali Davoodi, Erlendur Jónsson, Min Wu, Clare P. Grey and Roy G. Gordon. It was supported by the U.S. National Science Foundation through grant CBET-1914543, by U.S. DOE award DE-AC05-76RL01830 through PNNL subcontract 535264, and by a grant from the Massachusetts Clean Energy 393 Center.
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This is extremely good news. Solar and wind have enjoyed the social and political push with incentives, special tax treatment, etc and major media climate news to propel the economy into “renewables” without a real hard case being made for what taxpayers and ratepayers are actually getting for the costs. The picture is slowing and inexorably getting more clear and the facts aren’t going to be well received.
To hold some credibility the storage issue has to be addressed and pretty soon as well. The storage is going to have to really really really cheap.
So far, organic aqueous flow looks like the only tech with a chance of keeping wind and solar at grid level production measured over decades.
It more than just extremely good news, its critical news.
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