Harvard scientists reported superconductivity progress that’s more robust and operates at higher temperatures. The scientists successfully stacked three sheets of graphene and then twisted each of them at a specific angle to produce a three-layered structure more capable, robust and with a higher operating temperature than many of the double-stacked graphene designs.

Am artist’s rendition of twisted trilayer graphene. Image Credit: Polina Shmatkova and Margarita Davydova, Harvard University. Click image for the largest view.

In 2018, the physics world saw a discovery that when an ultrathin layer of carbon, called graphene, is stacked and twisted to a “magic angle,” that new double layered structure converts into a superconductor, allowing electricity to flow without resistance or energy waste. Now, in a literal twist, Harvard scientists have expanded on that superconducting system by adding a third layer and rotating it, opening the door for continued advancements in graphene-based superconductivity.

The work is described in a new paper in Science and should one day help lead toward superconductors that operate at higher or even close to room temperature. These superconductors are considered the holy grail of condensed matter physics since they would allow for tremendous technological revolutions in many areas including electricity transmission, transportation, and quantum computing. Most superconductors today, including the double layered graphene structure, work only at ultracold temperatures.

One of the paper’s co-lead authors Andrew Zimmerman, a postdoctoral researcher in working in the lab of Harvard physicist Philip Kim said, “Superconductivity in twisted graphene provides physicists with an experimentally controllable and theoretically accessible model system where they can play with the system’s properties to decode the secrets of high temperature superconductivity.”

Graphene is a one-atom-thick layer of carbon atoms that is 200 times stronger than steel yet is extremely flexible and lighter than paper. It has almost always been known to be a good conductor of heat and electrical current but is notoriously difficult to handle. Experiments unlocking the puzzle of twisted bilayer graphene have been ongoing since MIT physicist Pablo Jarillo-Herrero and his group pioneered the emerging field of “twistronics” with their experiment in 2018 where they produced the graphene superconductor by twisting it to a magic angle of 1.1 degrees.

The Harvard scientists report successfully stacking three sheets of graphene and then twisting each of them at that magic angle to produce a three-layered structure that is not only capable of superconductivity but does so more robustly and at higher temperatures than many of the double-stacked graphene. The new and improved system is also sensitive to an externally applied electric field that allows them to tune the level of superconductivity by adjusting the strength of that field.

The study’s other lead author Zeyu Hao, a Ph.D. student in the Graduate School of Arts and Sciences also working in the Kim Group said, “It enabled us to observe the superconductor in a new dimension and provided us with important clues about the mechanism that’s driving the superconductivity.”

One of those mechanisms has the theorists really excited. The trilayer system showed evidence that its superconductivity is due to strong interactions between electrons as opposed to weak ones. If true, this can not only help open a path to high temperature superconductivity but possible applications in quantum computing.

Eslam Khalaf, a co-author on the study and postdoctoral fellow working in the lab of Harvard physics professor Ashvin Vishwanath explained, “In most conventional superconductors, electrons move with a high speed and occasionally cross-paths and influence each other. In this case, we say their interaction effects are weak, While weakly interacting superconductors are fragile and lose superconductivity when heated to a few Kelvins, strong coupling superconductors are much more resilient but much less understood. Realizing strong coupling superconductivity in a simple and tunable system such as trilayer could pave the way to finally develop a theoretical understanding of strongly-coupled superconductors to help realize the goal of a high temperature, maybe even room temperature, superconductor.”

The researchers plan on continuing to explore the nature of this unusual superconductivity in further studies.

“The more we understand, the better we have chance to increase the superconducting transition temperatures,” said Kim.

One simply likely would think that superconductive materials will be mainstream products someday. This research gets the operating temperature up to -271° C or -456° F, which is still mighty cold for things like transmission lines, making that idea impractical. With so much energy lost to line loss for example and the opportunities for higher efficiencies, there is no doubt the research and ideas are going to keep coming.


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