A Helmholtz-Zentrum Berlin (HBZ) für Materialien und Energie team has demonstrated that hybrid halide perovskites crystallize without an inversion center. Interactions between the organic molecules and adjacent iodine atoms can lead to the formation of ferroelectric domains, which, indirectly, can result in higher solar-cell efficiencies. The formation of these ferroelectric domains cannot occur in purely inorganic perovskites.

The drawing illustrates the interaction of the organic methylammonium cation (CH3NH3+) with the surrounding iodide ions. The shift of the iodide atoms out of the common plane with lead causes the breaking of the inversion symmetry. Image Credit: HBZ. Click image for the largest view.

The research group’s study paper has been published in the journal Angewandte Chemie International Edition.

Solar cells based on perovskites have reached enormously high efficiencies within only a few years. Those containing hybrid halide perovskite, i.e. materials containing inorganic and organic components, achieve particularly high efficiencies, but lack long-term stability, so far. Even though inorganic perovskite semiconductors, such as CsPbI3, are less efficient, they are considered interesting, as well, since they may overcome the stability issues of hybrid perovskites.

Up to now, it was assumed that hybrid and purely inorganic perovskites do not differ fundamentally in their crystalline structure. When producing perovskite materials, it often occurs that no large single crystals are formed, but countless tiny twin crystals instead. This makes a crystal structure analysis particularly complicated and prone to errors and low precision.

An HZB team headed by Prof Susan Schorr and Dr Joachim Breternitz have now achieved a breakthrough in understanding the crystalline structure of hybrid halide perovskites. The team investigated crystalline samples of methylammonium lead iodide (MAPbI3), the most prominent representative of this class of materials, at the Diamond Light Source synchrotron (DLS) in the United Kingdom using high-resolution single-crystal diffraction. This approach provided data for a more in-depth analysis of the crystalline structure of this material.

They were also able to clarify, whether ferroelectric effects are possible at all in this hybrid halide perovskite. Ferroelectric domains can have favorable effects in solar cells and increase their efficiency. However, measuring this effect in samples is difficult – a null result can mean that there is either no ferroelectric effect or that the ferroelectric domains cancel one another’s effects out.

Breternitz explained, “From a crystallographic point of view, some conditions are necessary for ferroelectricity: a ferroelectric effect can only occur if the crystal structure does not contain an inversion center, and additionally if it exhibits a permanent polar moment.”

Previously, it was assumed that the crystal structure of MAPbI3 did contain an inversion center. However, the results of the crystal structure analysis show this is not the case: “The organic methylammonium cation MA+ plays a major role in this,” explains Breternitz. This is because the MA molecule is not spherically symmetrical and is also considerably larger than a single atom, so that it generates a polar moment with the adjacent iodine atoms. The occurrence of ferroelectric domains in MAPbI3 is therefore possible.

For inorganic perovskites incorporating an alkali atom instead of the MA molecule, this mechanism is not applicable. That means the more stable inorganic perovskites may be fundamentally somewhat more limited in their efficiency than their hybrid halide relatives.

The perovskite march just keeps on coming, stronger it seems each year. Yet there is a paucity of perovskite cells on the market. This situation can’t last much longer, as perovskite is thought to be much lower cost albeit with a shorter lifespan than silicon. They say time will tell, but the silicon foundries have to be concerned and consumers filled with hope.


1 Comment so far

  1. Ajay Verma on December 16, 2019 5:34 AM

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