Researchers at Kyoto University, along with colleagues at the University of Tokyo and Jiangsu Normal University in China have developed a new material that can selectively capture carbon dioxide (CO2) molecules and efficiently convert them into useful organic materials.

This new porous coordination polymer has propeller-shaped molecular structures that enables selectively capturing CO2, and efficiently convert the CO2 into useful carbon materials. Image Credit: Illustration by Mindy Takamiya. Kyoto University. Click image for the largest view.

The team’s study paper has been published in the journal Nature Communications.

The press release asserts “Human consumption of fossil fuels has resulted in rising global CO2 emissions, leading to serious problems associated with global warming and climate change. One possible way to counteract this is to capture and sequester carbon from the atmosphere, but current methods are highly energy intensive.” The low reactivity of CO2 makes it difficult to capture and convert it efficiently.

Ken-ichi Otake, Kyoto University materials chemist from the Institute for Integrated Cell-Material Sciences (iCeMS) said, “We have successfully designed a porous material which has a high affinity towards CO2 molecules and can quickly and effectively convert it into useful organic materials.”

The material is a porous coordination polymer (PCP, also known as MOF; metal-organic framework), a framework consisting of zinc metal ions. The researchers tested their material using X-ray structural analysis and found that it can selectively capture only CO2 molecules with ten times more efficiency than other PCPs.

The material has an organic component with a propeller-like molecular structure, and as CO2 molecules approach the structure, they rotate and rearrange to permit CO2 trapping, resulting in slight changes to the molecular channels within the PCP – this allows it to act as molecular sieve that can recognize molecules by size and shape. The PCP is also recyclable; the efficiency of the catalyst did not decrease even after 10 reaction cycles.

Susumu Kitagawa, materials chemist at Kyoto University said, “One of the greenest approaches to carbon capture is to recycle the carbon dioxide into high-value chemicals, such as cyclic carbonates which can be used in petrochemicals and pharmaceuticals.”

After capturing the carbon, the converted material can be used to make polyurethane, a material with a wide variety of applications including clothing, domestic appliances and packaging.

This work highlights the potential of porous coordination polymers for trapping carbon dioxide and converting into useful materials, opening up an avenue for future research into carbon capture materials.

This is fascinating work in CO2 recycling with an unusual result. A yield of polyurethane quite catches one with a surprise. Perhaps one day we’ll be using CO2 collectors for carbon collection at everyone’s home. Or perhaps not, CO2 is the fundamental food for plants. The source of the food we eat and the oxygen we breath.


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