Lawrence Berkeley National Laboratory Laboratory scientists have found a way to engineer the atomic-scale chemical properties of a water-splitting catalyst for integration with a solar cell. The result is a big boost to the stability and efficiency of artificial photosynthesis.

Schematic of the multi-functional water splitting catalyst layer engineered using atomic layer deposition for integration with a high-efficiency silicon cell. Image Credit: Ian Sharp at the Berkeley Lab. Click image for the largest view.

Schematic of the multi-functional water splitting catalyst layer engineered using atomic layer deposition for integration with a high-efficiency silicon cell. Image Credit: Ian Sharp at the Berkeley Lab. Click image for the largest view.

Led by researchers at the Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab), the project is described in a paper published this week in the journal Nature Materials.

The research comes out of the Joint Center for Artificial Photosynthesis (JCAP), a DOE Energy Innovation Hub established in 2010 to develop a cost-effective method of turning sunlight, water, and carbon dioxide into fuel. JCAP is led by the California Institute of Technology with Berkeley Lab as a major partner.

The goal of this study was to strike a careful balance between the contradictory needs for efficient energy conversion and chemically sensitive electronic components to develop a viable system of artificial photosynthesis to generate clean fuel.

Study principal investigator Ian Sharp, head of materials integration and interface science research at JCAP said, “In order for an artificial photosystem to be viable, we need to be able to make it once, deploy it, and have it last for 20 or more years without repairing it.”

The problem is that the active chemical environments needed for artificial photosynthesis are damaging to the semiconductors used to capture solar energy and power the device.

Sharp, who is also a staff scientist at Berkeley Lab’s Chemical Sciences Division explained, “Good protection layers are dense and chemically inactive. That is completely at odds with the characteristics of an efficient catalyst, which helps to split water to store the energy of light in chemical bonds. The most efficient catalysts tend to be permeable and easily transform from one phase to another. These types of materials would usually be considered poor choices for protecting electronic components.”

By engineering an atomically precise film so that it can support chemical reactions without damaging sensitive semiconductors, the researchers managed to satisfy contradictory needs for artificial photosystems.

Study lead author Jinhui Yang, who conducted the work as a postdoctoral researcher at JCAP pointed out, “This gets into the key aspects of our work. We set out to turn the catalyst into a protective coating that balances these competing properties.”

The researchers knew they needed a catalyst that could not only support active and efficient chemical reactions, but one that could also provide a stable interface with the semiconductor, allow the charge generated by the absorption of light from the semiconductor to be efficiently transferred to the sites doing catalysis, and permit as much light as possible to pass through.

They turned to a manufacturing technique called plasma-enhanced atomic layer deposition, performed at the Molecular Foundry at Berkeley Lab. This type of thin-film deposition is used in the semiconductor industry to manufacture integrated circuits.

Yang said, “This technique gave us the level of precision we needed to create the composite film. We were able to engineer a very thin layer to protect the sensitive semiconductor, then atomically join another active layer to carry out the catalytic reactions, all in a single process.”

The first layer of the film consisted of a nanocrystalline form of cobalt oxide that provided a stable, physically robust interface with the light-absorbing semiconductor. The other layer was a chemically reactive material made of cobalt dihydroxide.

Sharp said, “The design of this composite coating was inspired by recent advances in the field that have revealed how water-splitting reactions occur, at the atomic scale, on materials. In this way, mechanistic insights guide how to make systems that have the functional properties we need.”

Using this configuration, the researchers could run photosystems continuously for three days – potentially longer – when such systems would normally fail in mere seconds.

Yang summed up with, “A major impact of this work is to demonstrate the value of designing catalysts for integration with semiconductors. Using a combination of spectroscopic and electrochemical methods, we showed that these films can be made compact and continuous at the nanometer scale, thus minimizing parasitic light absorption when integrated on top of photoactive semiconductors.”

The study authors noted that while this is an important milestone, there are many more steps needed before a commercially viable artificial photosystem is ready for deployment.

Sharp explained, “In general, we need to know more about how these systems fail so we can identify areas to target for future improvement. Understanding degradation is an important avenue to making something that is stable for decades.”

This is a remarkable achievement – six years in the making – but nevertheless a worthwhile effort. Congratulations are in order with hopes that the development will work as well or better and the device will scale in an economically useful way.


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