Massachusetts Institute of Technology researchers propose that an advanced manufacturing approach for lithium-ion batteries promises to significantly slash the cost of the most widely used type of rechargeable batteries while also improving their performance and making them easier to recycle.

Researchers at MIT and at a spinoff company called 24M with a pilot manufacturing plant setup, promise to significantly slash the cost of the most widely used type of rechargeable batteries.

Semisolid Lithium Ion Battery Pilot Production Line.  A pilot manufacturing plant at 24M's headquarters in Cambridge has produced thousands of test batteries to demonstrate the efficiency of the new design. Image Credit: 24M.  Click image for the largest view.

Semisolid Lithium Ion Battery Pilot Production Line. A pilot manufacturing plant at 24M’s headquarters in Cambridge has produced thousands of test batteries to demonstrate the efficiency of the new design.
Image Credit: 24M. Click image for the largest view.

Yet-Ming Chiang, the Kyocera Professor of Ceramics at MIT and a co-founder of 24M who was also a co-founder of the battery company A123 said, “We’ve reinvented the process.”

This group is likely on to something.

Chiang explained the existing process for manufacturing lithium-ion batteries has hardly changed in the two decades since the technology was invented, and is inefficient, with more steps and components than are really needed.

The new process is based on a concept developed five years ago by Chiang and colleagues including W. Craig Carter, the POSCO Professor of Materials Science and Engineering. The concept is the so-called “flow battery,” where the electrodes are suspensions of tiny particles carried by a liquid and pumped through various compartments of the battery.

The new battery design is a hybrid between flow batteries and conventional solid ones. In this version, while the electrode material does not flow, it is composed of a similar semisolid, colloidal suspension of particles.  Chiang and Carter refer to this as a “semisolid battery.” This approach greatly simplifies manufacturing, and also makes batteries that are flexible and resistant to damage.

Chiang is senior author of the study paper published in the Journal of Power Sources. The paper also analyzes the tradeoffs involved in choosing between solid and flow-type batteries, depending on their particular applications and chemical components.

The analysis demonstrates that while a flow-battery system is appropriate for battery chemistries with a low energy density (those that can only store a limited amount of energy for a given weight), for high-energy-density devices such as lithium-ion batteries, the extra complexity and components of a flow system would add unnecessary extra cost.

Chiang noted that almost immediately after publishing the earlier research on the flow battery, “We realized that a better way to make use of this flowable electrode technology was to reinvent the [lithium ion] manufacturing process.”

Instead of the standard method of applying liquid coatings to a roll of backing material, and then having to wait for that material to dry before it can move to the next manufacturing step, the new process keeps the electrode material in a liquid state and requires no drying stage at all. Using fewer, thicker electrodes, the system reduces the conventional battery architecture’s number of distinct layers, as well as the amount of nonfunctional material in the structure, by 80 percent.

Having the electrode in the form of tiny suspended particles instead of consolidated slabs greatly reduces the path length for charged particles as they move through the material – a property known as “tortuosity.” A less tortuous path makes it possible to use thicker electrodes, which, in turn, simplifies production and lowers cost.

Chiang explained that in addition to streamlining manufacturing enough to cut battery costs by half, the new system produces a battery that is more flexible and resilient. While conventional lithium-ion batteries are composed of brittle electrodes that can crack under stress, the new formulation produces battery cells that can be bent, folded or even penetrated by bullets without failing. This should improve both safety and durability, he said.

The company has so far made about 10,000 batteries on its prototype assembly lines, most of which are undergoing testing by three industrial partners, including an oil company in Thailand and Japanese heavy-equipment manufacturer IHI Corp. The process has received eight patents and has 75 additional patents under review; 24M has raised $50 million in financing from venture capital firms and a U.S. Department of Energy grant.

The company is initially focusing on grid-scale installations, used to help smooth out power loads and provide backup for renewable energy sources that produce intermittent output, such as wind and solar power. But Chiang said the technology is also well suited to applications where weight and volume are limited, such as in electric vehicles.

Chiang also added another advantage of this approach that factories using the method can be scaled up by simply adding identical units. With traditional lithium-ion production, plants must be built at large scale from the beginning in order to keep down unit costs, so they require much larger initial capital expenditures. By 2020, Chiang estimates that 24M will be able to produce batteries for less than $100 per kilowatt-hour of capacity.

The third party view comes from Venkat Viswanathan, an assistant professor of mechanical engineering at Carnegie Mellon University who was not involved in this work. Viswanathan said the analysis presented in the new paper “addresses a very important question of when is it better to build a flow battery versus a static model . . . This paper will serve as a key tool for making design choices and go-no go decisions.”

Viswanathan added that 24M’s new battery design “could do the same sort of disruption to [lithium ion] batteries manufacturing as what mini-mills did to the integrated steel mills.”

Working with Chiang, the Power Sources paper was co-authored by graduate student Brandon Hopkins, mechanical engineering professor Alexander Slocum, and Kyle Smith of the University of Illinois at Urbana-Champaign.

It looks like this technology has legs and they are already walking into the market place. Congratulations are in order. Maybe they’ll make one someday that keeps my smart phone alive for a full day.


1 Comment so far

  1. Parc Life EC on September 15, 2015 4:14 AM

    This is surely a great saving for many people out there. Technology has imporved so much these few years. These rechargeable batteries is a breakthru with so many added advantages.

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