Dec
31
Explanation Begins for the Superconducting Pseudogap
December 31, 2014 | Leave a Comment
The pseudogap takes electrons from superconducting materials that otherwise might pair up to carry current through a material with 100% efficiency.
The result is the culmination of 20 years of research aimed at finding out whether the pseudogap helps or hinders superconductivity, which could transform society by making electrical transmission, computing and other electrical powered work much more energy efficient.
Lead author Makoto Hashimoto, a staff scientist at SLAC’s Stanford Synchrotron Radiation Lightsource (SSRL), the DOE Office of Science User Facility where the experiments were carried out explained the new study definitively shows that the pseudogap is one of the things that stands in the way of getting superconductors to work at higher temperatures for everyday uses. The results have been published in Nature Materials.
Hashimoto said, “Now we have clear, smoking-gun evidence that the pseudogap phase competes with and suppresses superconductivity. If we can somehow remove this competition, or handle it better, we may be able to raise the operating temperatures of these superconductors.”
In the experiments, researchers used a technique called angle-resolved photoemission spectroscopy, or “ARPES”, to knock electrons out of a copper oxide material, one of a handful of materials that superconduct at relatively high temperatures – although they still have to be cooled to at least minus 135ยบ C.
Plotting the energies and momenta of the ejected electrons tells researchers how they were behaving when they were inside the material. In metals, for instance, electrons freely flow around and between atoms. In insulators they stick close to their home atoms. In superconductors electrons leave their usual positions and pair up to conduct electricity with zero resistance and 100% efficiency. The missing electrons leave a characteristic gap in the researchers’ plots.
During the mid-1990s scientists discovered another puzzling gap in their plots of copper oxide superconductors. This “pseudogap” looked like the one left by superconducting electrons, but it showed up at temperatures too warm for superconductivity to occur. Was it a lead-in to superconducting behavior? A rival state that held superconductivity at bay? Where did it come from? No one knew.
Zhi-Xun Shen, a professor at SLAC and Stanford and senior author of the study offers the overview, “It’s a complex, intimate relationship. These two phenomena likely share the same roots but are ultimately antagonistic. When the pseudogap is winning, superconductivity is losing ground.”
Shen and his colleagues have been using ARPES to investigate the pseudogap ever since it showed up, refining their techniques over the years to pry more information out of the flying electrons.
In this latest study, Hashimoto was able to find out exactly what was happening at the moment the material transitioned into a superconducting state. He did this by measuring not only the energies and momenta of the electrons, but the number of electrons coming out of the material with particular energies over a wide range of temperatures, and after the electronic properties of the material had been altered in various ways.
He discovered clear, strong evidence that at this crucial transition temperature, the pseudogap and superconductivity are competing for electrons. Then theoretical calculations by members of the team were able to reproduce this complex relationship.
Thomas Devereaux, a professor at Stanford and SLAC and co-author of the study explained, “The pseudogap tends to eat away the electrons that want to go into the superconducting state. The electrons are busy doing the dance of the pseudogap, and superconductivity is trying to cut in, but the electrons are not letting that happen. Then, as the material goes into the superconducting state, the pseudogap gives up and spits the electrons back out. That’s really the strongest evidence we have that this competition is occurring.”
Now scientists can measure, but still don’t know what causes the pseudogap. Devereaux said, “This remains one of the most important questions in the field, because it’s clearly preventing superconductors from working at even higher temperatures, and we don’t know why.”
Everyone will agree, the team believes the results open and pave new directions for further research.
Hashimoto said, “Now we can model the competition between the pseudogap and superconductivity from the theoretical side, which was not possible before. We can use simulations to reproduce the kinds of features we have seen, and change the variables within those simulations to try to pin down what the pseudogap is. Competition may be only one aspect of the relationship between the two states. There may be more profound questions – for example, whether the pseudogap is necessary for superconductivity to occur.”
Now we know the pseudogap is there and what happens as temperatures invoke its occurrence. The right questions are possible and progress can come with experimentation.
Its been a long time coming, which makes the team’s success very sweet, indeed.