Lawrence Livermore National Laboratory (LLNL) has found a new catalyst that helps extract hydrogen from water efficiently and cheaply. The team of scientists at LLNL collaborated with scientists at Rice University and San Diego State University.

The team turned to electricity to produce clean hydrogen fuel by splitting water molecules, which are made of oxygen and hydrogen atoms. The researchers discovered a new class of cheap and efficient catalyst to facilitate the water splitting process. The research paper has been published in Nature Energy.

Hydrogen gas bubbles evolve from water at tantalum disulfide electrocatalyst surfaces. Catalytic activity in layered metal dichalcogenides like these is usually limited to edges, but this work reports new materials that also can generate hydrogen at the surfaces. Image Credit: Ryan Chen at LLNL. Click image for the largest view.

LLNL lead author Brandon Wood said, “Hydrogen gas has immense potential as a source of sustainable fuel, because it generates no carbon emissions. It can be produced from multiple sources, but the holy grail is to make it from water.”

Wood also is a principal investigator in the Department of Energy Office of Energy Efficiency and Renewable Energy’s (EERE) HydroGEN Advanced Water Splitting Materials Consortium, an Energy Materials Network node focused on hydrogen production from water.

Extracting hydrogen from water using electricity is a fairly straightforward process, but it is inefficient and usually takes a lot of energy. The efficiency can be improved using catalysts, which are often made of expensive precious metals, such as platinum.

So the LLNL team sought to come up with a cheaper way to efficiently split the water molecules.

To solve the problem, Wood and lead author Yuanyue Liu – a LLNL summer intern with Wood – turned to a class of catalysts based on transition-metal dichalcogenides (MX2), which have generated a great deal of interest for water splitting. The issue with the MX2 materials that currently are used (based on molybdenum and tungsten) is that only the exposed edges of the catalysts are active.

Wood, Liu and colleagues new take on the problem is using quantum-mechanical calculations to reveal underlying electronic factors that would make the entire surfaces of the MX2 materials active for catalysis. These “descriptors” were then used to computationally screen MX2 candidates that could make better water-splitting catalysts.

Researchers from Rice University experimentally validated the calculations by synthesizing and testing two of the proposed materials, tantalum disulfide and niobium disulfide. Beyond confirming that the materials’ surfaces were active towards water splitting, they discovered that the materials had an unusual ability to optimize their shape as they evolved hydrogen gas. This allowed the materials to achieve even better performance.

“The self-optimizing behavior and surface activity mean high performance can be achieved with only minimal catalyst loading,” Wood said. “It’s a huge advantage for scalable processing, since there’s no need to turn to expensive techniques like nanostructuring. Our work opens the door to using this type of catalyst, and our theoretical descriptor should make it easy to assess water-splitting activity in similar classes of layered materials.”

Hopeful indeed. The research intensity for freeing hydrogen from water is impressive. Yet the technology choices look pretty good already. The issue yet to be solved is hydrogen storage. That’s a field watched every day with long empty saddening gaps of nothing happening that runs months long. Hydrogen is still badly crippled competitively until storage ideas that are effective and economic are scaleable.


1 Comment so far

  1. stabilized soil mixing plant on September 13, 2017 10:42 PM

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