Jan
24
Big Leap Forward For Lithium Sulfur Cell Batteries
January 24, 2018 | 2 Comments
Lawrence Berkeley National Laboratory researchers have reported that a new lithium-sulfur battery component allows a doubling in capacity compared to a conventional lithium-sulfur battery, even after more than 100 charge cycles.
Lithium-sulfur batteries are promising candidates for replacing today’s common lithium-ion batteries in electronics and electric vehicles since they are cheaper, weigh less, and can store nearly double the energy for the same mass. So far lithium-sulfur batteries become unstable over time, and their electrodes deteriorate, limiting widespread adoption.
This illustration shows the formation of complex ion clusters during the cycling of a lithium-sulfur battery cell. The clusters consist of cationic polymer binders, battery electrolyte, and anionic sulfur-active materials. Image Credit: Berkeley Lab. Click image for the largest view.
The lithium-sulfur battery component allows a doubling in capacity compared to a conventional lithium-sulfur battery, even after more than 100 charge cycles at high current densities, which are key performance metrics for their adoption in electric vehicles (EVs) and in aviation.
They did it by designing a new polymer binder that actively regulates key ion transport processes within a lithium-sulfur battery, and have also shown how it functions on a molecular level. The work has been published in Nature Communications.
Brett Helms, a staff scientist at Berkeley Lab’s Molecular Foundry and corresponding author of the study said, “The new polymer acts as a wall. The sulfur is loaded into the pores of a carbon host, which are then sealed by our polymer. As sulfur participates in the battery’s chemical reactions, the polymer prevents the negatively charged sulfur compounds from wandering out. The battery has great promise for enabling the next generation of EVs.”
When a lithium-sulfur battery stores and releases energy, the chemical reaction produces mobile molecules of sulfur that become disconnected from the electrode, causing it to degrade and ultimately lowering the battery’s capacity over time. To make these batteries more stable, researchers have traditionally worked to develop protective coatings for their electrodes, and to develop new polymer binders that act as the glue holding battery components together. These binders are intended to control or mitigate the electrode’s swelling and cracking.
The Berkeley Lab’s new binder goes a step further. Researchers from the Organic Synthesis Facility at Berkeley Lab’s Molecular Foundry, a research center specializing in nanoscale science, designed a polymer to keep the sulfur in close proximity to the electrode by selectively binding the sulfur molecules, counteracting its migratory tendencies.
The next step was to understand the dynamic structural changes that are likely to occur during charging and discharging as well as at different states of charge. David Prendergast, who directs the Foundry’s Theory Facility, and Tod Pascal, a project scientist in the Theory Facility, built a simulation to test the researchers’ hypotheses about the polymer’s behavior.
“We can now reliably and efficiently model sulfur chemistry within these binders based on learning from detailed quantum mechanical simulations of the dissolved sulfur-containing products,” stated Prendergast.
Their large-scale molecular dynamics simulations, conducted on supercomputing resources at Berkeley Lab’s National Energy Research Scientific Computing Center (NERSC), confirmed that the polymer has an affinity for binding the mobile sulfur molecules, and also predicted that the polymer would likely show a preference for binding different sulfur species at different states of charge for the battery. Experiments conducted at Berkeley Lab’s Advanced Light Source and Argonne National Laboratory’s Electrochemistry Discovery Lab confirmed these predictions.
The research team took their study one step further by also examining the performance of lithium-sulfur cells made with the new polymer binder. Through a set of experiments, they were able to analyze and quantify how the polymer affects the chemical reaction rate in the sulfur cathode, which is key to achieving high current density and high power with these cells.
By nearly doubling the battery’s electrical capacity over long-term cycling, the new polymer raises the bar on the capacity and power of lithium-sulfur batteries.
The combined understanding of the synthesis, theory, and characteristics of the new polymer have made it a key component in the prototype lithium-sulfur cell at DOE’s Joint Center for Energy Storage Research (JCESR).
We have to hope that this technology or the further developed form can go commercial. Doubling capacity, cutting production costs and extending the extent to which the world’s lithium supply can be used are fundamental economic factors that deserve continued efforts. Lets hope the cycle life can get into the thousands – that’s another attribute this writer hopes battery technology can get to.
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Useful post! Lets hope the cycle life can get into the thousands – that’s another attribute this writer hopes battery technology can get to.
Usable Power density ?