Researchers at the University of Maryland and the U.S. Army Research Laboratory have developed a lithium-ion battery that uses a water-salt solution as its electrolyte. The chemistry solution also reaches the 4.0 volt mark desired for household electronics, such as laptop computers, without the fire and explosive risks associated with some commercially available non-aqueous lithium-ion batteries.

The details have been published in a paper by the new journal JOULE, a new interdisciplinary journal from Cell Press.

Salt Water Gel Electrolyte Over Lithium Metal. Image Credit: University of Maryland. Click image for the largest view.

Co-senior author Kang Xu, a lab fellow at the U.S. Army Research Laboratory specializing in electrochemistry and materials science explains, “In the past, if you wanted high energy, you would choose a non-aqueous lithium-ion battery, but you would have to compromise on safety. If you preferred safety, you could use an aqueous battery such as nickel/metal hydride, but you would have to settle for lower energy. Now, we are showing that you can simultaneously have access to both high energy and high safety.”

The research follows a 2015 study in Science that produced a similar 3.0 volt battery with an aqueous electrolyte but was stymied from achieving higher voltages by the so-called “cathodic challenge,” in which one end of the battery, made from either graphite or lithium metal, is degraded by the aqueous electrolyte. To solve this problem and make the leap from three volts to four, the first author, University of Maryland assistant research scientist Chongyin Yang, designed a new gel polymer electrolyte coating that can be applied to the graphite or lithium anode.

This hydrophobic coating expels water molecules from the vicinity of the electrode surface and then, upon charging for the first time, decomposes and forms a stable interphase – a thin mixture of breakdown products that separates the solid anode from the liquid electrolyte. This interphase, inspired by a layer generated within non-aqueous batteries, protects the anode from debilitating side reactions, allowing the battery to use desirable anode materials, such as graphite or lithium metal, and achieve better energy density and cycling ability.

Co-senior author Chunsheng Wang, Professor of Chemical & Biomolecular Engineering at the University of Maryland’s A. James Clark School of Engineering said, “The key innovation here is making the right gel that can block water contact with the anode so that the water doesn’t decompose and can also form the right interphase to support high battery performance.”

The addition of the gel coating also boosts the safety advantages of the new battery when compared to standard non-aqueous lithium-ion batteries and boosts the energy density when compared to any other proposed aqueous lithium-ion batteries. All aqueous lithium-ion batteries benefit from the inflammability of water-based electrolytes as opposed to the highly flammable organic solvents used in their non-aqueous counterparts.

Unique to this one, however, is that even when the interphase layer is damaged (if the battery casing were punctured, for instance), it reacts slowly with the lithium or lithiated graphite anode, preventing the smoking, fire, or explosion that could otherwise occur if a damaged battery brought the metal into direct contact with the electrolyte.

Though the power and energy density of the new battery are suitable for commercial applications currently served by more hazardous non-aqueous batteries, certain improvements would make it even more competitive. In particular, the researchers would like to increase the number of full-performance cycles that the battery can complete and to reduce material expenses where possible. “Right now, we are talking about 50-100 cycles, but to compare with organic electrolyte batteries, we want to get to 500 or more,” Wang said.

The researchers also note that the electrochemical manipulations behind the jump to four volts have importance within battery technology and beyond.

“This is the first time that we are able to stabilize really reactive anodes like graphite and lithium in aqueous media,” said Xu. “This opens a broad window into many different topics in electrochemistry, including sodium-ion batteries, lithium-sulfur batteries, multiple ion chemistries involving zinc and magnesium, or even electroplating and electrochemical synthesis; we just have not fully explored them yet.”

This fresh birthed technology has immense potential. Your humble writer also wishes to welcome the new journal for publications. Its definitively a very good day for battery researchers and those of us curious as to what is going on and coming up.


Comments

4 Comments so far

  1. Automatic Waste Segregation Machine on September 12, 2017 1:31 AM

    Its definitively a very good day for battery researchers and those of us curious as to what is going on and coming up. Great post! Thanks for sharing.

  2. JavelinaTex on September 12, 2017 11:17 AM

    “All aqueous lithium-ion batteries benefit from the inflammability of water-based electrolytes as opposed to the highly flammable organic solvents used in their non-aqueous counterparts.”

    Inflammability is the same as flammability. It’s confusing, but the former goes back to Latin and the later is more properly understood in English.

    http://www.dictionary.com/browse/inflammability

    Need to correct text as water doesn’t burn and that is the whole point.

  3. Waste plastic to diesel machine Swaziland on September 13, 2017 8:59 PM

    Good post! Keep updating!

  4. block making machine on September 13, 2017 10:37 PM

    Electricity is a useful source and energy, we should not only use it properly, but look for new energy.

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